terça-feira, 28 de agosto de 2007

Classificação e Reações dos óxidos

Óxidos Básicos

Definição:
São óxidos em que o elemento ligado ao oxigênio é um metal com baixo número de oxidação (+1,+2 e+3). Os óxidos de caráter mais básico são os óxidos de metais alcalinos e alcalino-terrosos. Os óxidos básicos possuem estrutura iônica devido à diferença de eletronegatividade entre o metal (que é baixa) e o oxigênio (que é alta), por terem este caráter iônico apresentam estado físico sólido. Alguns exemplos:

Na2O óxido de sódio
CaO óxido de cálcio (cal viva)
BaO óxido de bário (barita)
CuO óxido de cobre II (óxido cúprico)
Cu2O óxido de cobre I (cuprita)
FeO óxido de ferro II (óxido ferroso)

Reações
Reagem com a água formando uma base e com ácidos formando sal e água (neutralizando o ácido). Exemplos:

Na2O + H2O 2NaOH
K2O + H2O 2KOH
CaO + H2O Ca(OH)2
FeO + H2O Fe(OH)2
Na2O + 2HNO3 2NaNO3 + H2O
Cu2O + 2HCl 2CuCl + H2O
CaO + H2SO4 CaSO4 + H2O
3FeO + 2H3PO4 Fe3(PO4)2 + 3H2O

Óxidos Ácidos ou Anidridos

Definição:
São óxidos em que o elemento ligado ao oxigênio é um semi-metal ou metal com alto número de oxidação (nox > +4) ou qualquer não-metal. Possuem estrutura molecular, pois a diferença de eletronegatividade entre o oxigênio e o outro elemento não é tão grande. Resultam da desidratação dos ácidos e, por isso, são chamados anidridos de ácidos. Alguns exemplos:

CO2 óxido de carbono IV ou dióxido de (mono)carbono ou anidrido carbônico
SO2 óxido de enxofre IV ou dióxido de (mono)enxofre ou anidrido sulfuroso.
SO3 óxido de enxofre VI ou trióxido de (mono)enxofre ou anidrido sulfúrico.
Cl2O óxido de cloro I ou monóxido de dicloro ou anidrido hipocloroso.
Cl2O7 óxido de cloro VII ou heptóxido de dicloro ou anidrido perclórico.
SiO2 óxido de silício ou dióxido de (mono)silício ou anidrido silícico.
MnO3 óxido de manganês VI ou trióxido de (mono)manganês
Mn2O7 óxido de manganês VII ou heptóxido de dimanganês ou anidrido permangânico.

Reações
Reagem com água formando um ácido oxigenado e com bases formando sal e água (neutralizando a base). Exemplos:

SO2 + H2O H2SO3
P2O5 + 3H2O 2H3PO4
N2O3 + H2O 2HNO2
CO2 + H2O H2CO3
SO2 + 2KOH K2SO3 + H2O
P2O5 + 6LiOH 2Li3PO4 + 3H2O
N2O3 + Ba(OH)2 Ba(NO2)2 + H2O
CO2 + Ca(OH)2 CaCO3 + H2O

Óxidos Anfóteros

Definição:
São óxidos de metais de transição e semi-metais capazes de reagir tanto com ácidos quanto com bases, fornecendo sal e água. Por possuírem propriedades intermediárias entre os óxidos ácidos e os óxido básicos, podem se comportar como óxidos ácidos e como básicos. Dependendo do metal ligado ao oxigênio pode haver predominância do caráter ácido ou básico. O caráter ácido do óxido aumenta à medida que seu elemento formador aproxima-se, na tabela periódica, dos não-metais. O caráter básico do óxido aumenta à medida que o elemento formador aproxima-se dos metais alcalinos e alcalino-terrosos. A estrutura dos óxidos anfóteros pode ser iônica ou molecular. Alguns exemplos:

SnO óxido de estanho II
SnO2 óxido de estanho IV
Fe2O3 óxido de ferro III
ZnO óxido de zinco
Al2O3 óxido de alumínio

Reações
Reagem com ácidos formando sal e água (o metal do óxido torna-se o cátion do sal), e com bases formando sal e água também (neste caso o metal formador do óxido torna-se o ânion do sal). Exemplos:

ZnO + H2SO4 ZnSO4 + H2O
ZnO + 2KOH K2ZnO2 + H2O
Al2O3 + 6HCl 2AlCl3 + 3H2O
Al2O3 + 2NaOH 2NaAlO2 + H2O
Alguns dos ânions formados são:

ZnO2-2 zincato
AlO2- aluminato
SnO2-2 estanito
SnO3-2 estanato
PbO2-2 plumbito
PbO3-2 plumbato
AsO3-3 arsenito
AsO4-3 arseniato


Óxidos Neutros

Definição:
São óxidos que não apresentam características ácidas nem básicas. Não reagem com água, nem com ácidos, nem com bases. O fato de não apresentarem caráter ácido ou básico não significa que sejam inertes. São formados por não-metais ligados ao oxigênio, e geralmente apresentam-se no estado físico gasoso. Alguns exemplos:

CO óxido de carbono II
NO óxido de nitrogênio II
N2O óxido de nitrogênio I - veja Óxido nitroso

Óxidos Duplos, Salinos ou Mistos

Definição:
São aqueles que originam dois óxidos ao serem aquecidos.

Quando reage-se um óxido duplo com um ácido, o produto formado é composto de dois sais de mesmo cátion, mas com nox diferentes, e mais água.


Peróxidos

Definição:
São os óxidos formados por cátions das famílias dos metais alcalinos (1A) e metais alcalinos terrosos (2A) e pelo oxigênio com nox igual a -1.

Um exemplo é o peróxido de hidrogênio (H2O2), componente da água oxigenada. Sua aplicação se dá em cortes e feridas que correm o risco de infecção bacteriana. A degradação do peróxido de hidrogênio pela enzima catalase libera oxigênio (O2) o que causa a morte de bactérias anaeróbeas. Exemplos:

Na2O2
BaO2

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